Calculate the Gibbs free energy for the given reaction, with the standard electrode potential equal to 1.1 V
\(Zn ( s )+ Cu ^{2+}( aq ) \rightarrow Zn ^{2+}( aq )+ Cu ( s )\)

Which will form the most stable complex ?

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Organic compounds derived from NH3 by replacing one or more H-atoms with alkyl or aryl groups will form primary, secondary and tertiary amines. The common methods which include their preparations are reduction of nitro group, amide group and nitrile group, Gabriel phthalimide synthesis and ammonolysis of alkyl halides. Amines are basic in nature due to the presence of a lone pair of electrons on the nitrogen atom. Important chemical properties of amines include acylation, alkylation and their interaction with nitrous acid. There are various tests which can distinguish different types of amines from each other, for e.g. carbylamine test, Hinsberg's test, coupling reaction etc. Another important class of compounds which can be derived from primary amines is azo compounds. These compounds are intensely colored and widely used as dyes in textile, leather and food industries.
Conversion of nitro group into primary amine is preferred using

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Carbohydrates are naturally formed organic compounds from various plants. The common chemical formula, \(C _x\left( H _2 O \right)_y\), was considered as hydrates of carbon to derive the various carbohydrates. For instance, the general formula for glucose ( \(C _6 H _{12} O _6\) ) easily fits into the above formula. Carbohydrates also called saccharides are classified on the basis of their behavior towards hydrolysis. Monosaccharides cannot be hydrolyzed further to simpler units of polyhydroxy aldehyde or ketones. About 20 monosaccharides are known to occur in nature. Carbohydrates that yield large number of monosaccharide units are called polysaccharides. Amino acids contain ( \(- NH _2\) ) and ( - COOH ), which can be classified in various forms. Proteins are polymers of alpha amino acids which are connected to each other by a peptide bond or peptide linkage. When a native protein is subjected to physical change, its globules unfold and helix get uncoiled and the protein loses its biological activity. The protein is said to be denaturated.
The two monosaccharides units are joined together through which linkage ?

Anisole on heating with concentrated HI gives:

The properties which depend on the number of solute particles irrespective of their nature relative to the total number of particles in the solution are called colligative properties. These are relative lowering of vapour pressure of the solvent, depression of freesing point of the solvent, elevation of boiling point of the solvent and osmotic pressure of the solution. All of these properties help in calculating the observed molar mass of the solute.
Determination of osmotic pressure is considered best for the determination of molecular mass of the solute.
Based on solute-solvent interactions, arrange the following in order of increasing solubility in n-octane.
(A) Cycloheptane
(B) NaCl
(C) \(CH _3 OH\)
(D) \(CH _3 CN\)
Choose the correct answer from the options given below :

Answer the question on the basis of passage given below :
Adsorption is a surface phenomenon and it differs from absorption which occurs throughout the body of the substance that absorbs. In physiosorption the attractive forces are mainly van der Waal's forces while in chemisorption ionic/covalent bonds are formed between particles of adsorbent and adsorbate. The catalytic activity of finely divided iron in Haber's process of ammonia manufacture can be explained by adsorption theory. Adsorption being an exothermic process, the heat of adsorption is utilised in enhancing the rate of the reaction. Adsorption has many applications being used in gas masks, control of humidity, chromatograph separation, curing diseases etc.
Which of the following is not correct regarding the adsorption of a gas on the surface of solid ?
(A) On increasing temperature, adsorption increases continuously.
(B) Enthalphy and entropy changes are negative.
(C) Chemical adsorption is more specific than physical adsorption.
(D) High temperature favours physical adsorption.
Choose the correct answer from the options given below :

Roman numbers in the names of restriction enzymes indicate -

The light rays travel from a glass slab with refractive index \( \mu_1 \) to the second slab with refractive index \( \mu_2 \). The refractive index of the second slab with respect to the first one is: (Assume that the two slabs have the same thickness)

An eye specialist prescribes spectacles having a combination of a converging lens of focal length 25 cm and a diverging lens of focal length of 20 cm. The power of the combination of two lenses (in dioptre) is

The function \(f(x) = |x - 1|\) is

Which of the following is the primary female sex organ?

If the system of equations \(2 x+3 y=10\) and \(x+k y=4\) has a unique solution, then