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CUET · CHEMISTRY · PYQ PAPER 2023

At a certain temperature, the value of the slope of the plot of osmotic pressure (\(\pi\)) against concentration (\(\text{C}\) in mol \(\text{L}^{-1}\)) of a certain polymer solution is 291R.
The temperature at which osmotic pressure is measured is

  1. A 271 \(^{\circ}\text{C}\)
  2. B 18 \(^{\circ}\text{C}\)
  3. C 564 K
  4. D 18 K
Verified Solution

Answer & Solution

Correct Answer

(B) 18 \(^{\circ}\text{C}\)

Step-by-step Solution

Detailed explanation

\(\pi = \text{iCRT}\) \(\frac{\text{d}\pi}{\text{dC}} = \text{iRT}\) \(\text{iRT} = 291\text{R}\) \(\text{T} = 291\text{ K}\) (assuming \(\text{i}=1\)) \(\text{T}_{^\circ\text{C}} = 291 - 273 = 18 \text{ }^\circ\text{C}\)
From CUET
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