Arrange the halogens in the increasing order of bond dissociation enthalpy :
(A) \(F_2\)
(B) \(Cl_2\)
(C) \(Br_2\)
(D) \(I_2\)
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Which among the following metals shows 6 secondary valencies ?
(A) 1 mole of \(PdCl _2 \cdot 4 NH _3\) reacts with excess of \(AgNO _3\) to give 2 moles of AgCl precipitated
(B) 1 mole of \(NiCl _2 \cdot 6 H _2 O\) reacts with excess of \(AgNO _3\) to give 2 moles of AgCl precipitated
(C) 1 mole of \(PtCl _4 \cdot 2 HCl\) does not give reaction with \(AgNO _3\)
(D) 1 mole of \(CoCl _3 \cdot 4 NH _3\) reacts with excess of \(AgNO _3\) to give 1 mole of AgCl precipitated
(E) 1 mole of \(PtCl _2 \cdot 2 NH _3\) does not give reaction with \(AgNO _3\)
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The entities which donot dissociate into simple ions are :
A. \([Fe(CN)_6]^{4-}\)
B. \(KCl \cdot MgCl_2 \cdot 6H_2O\)
C. \(K_4[Fe(CN)_6]\)
D. \(KAl(SO_4)_2 \cdot 12H_2O\)
E. \(FeSO_4 \cdot (NH_4)_2SO_4 \cdot 6H_2O\)
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How many aldol condensation products can be obtained when two aldehydes, both with a-hydrogen atoms undergo reaction?

Match List - I with List - II.

List - I	List - II
(A) Oxalic acid	(I) Hexane-1,6-dioic acid
(B) Acetophenone	(II)Ethane-1,2-dioic acid
(C) Phthalic acid	(III) Benzene-1,2-dicarboxylic acid
(D) Adipic acid	(IV) \(\Delta T_b=k_b m\)

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Arrange the following alcohols in increasing order of their boiling points.
(A) Propan-1-ol
(B) Butan-2-ol
(C) Butan-1-ol
(D) Pentan-1-ol
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Answer the question on the basis of passage given below :
Aldehydes and ketones represent two essential classes of organic compounds
which are extensively used in the synthesis of a wide variety of other organic molecules.
Due to the inherent polarity of the central carbonyl group, these substances readily undergo nucleophilic addition reactions.
Broadly speaking, these addition reactions can be categorized into two types:
one in which simple addition of the nucleophilic reagent occurs across the \(> C = O\) bond, and the second type where the initial addition is subsequently followed by the elimination of a water molecule.
A variety of ammonia derivatives, including hydroxylamine, hydrazine, phenylhydrazine,
2, 4-dinitroplhenylhdrazine, and semicarbagide, all belong to this second category of reactions.
These specific derivatives are fundamentally used for the identification and definitive characterization of aldehydes and ketones. Significantly, both types of nucleophilic addition reactions are strongly influenced by both steric and electronic factors.
As a general rule, aliphatic aldehydes exhibit higher reactivity compared to aromatic aldehydes.
The aliphatic aldehydes demonstrate the ability to reduce both Fehling's solution and Tollen's reagent, whereas aromatic aldehydes are limited to reducing only Tollen's reagent.
In a similar manner to aldehydes, aromatic ketones are observed to be less reactive than aliphatic ketones towards all nucleophilic addition reactions.
In a separate context, phenols and carboxylic acids both exhibit acidic properties in nature.
Both classes of compounds readily dissolve in NaOH solution and cause blue litmus to turn red.
However, carboxylic acids stand out as much stronger acids than phenols and thus can decompose sodium bicarbonate \(\left( NaHCO _3\right)\) with the distinct evolution of \(CO _2\) gas, a reaction which phenols do not undergo.
It is important to note that both electron- donating and electron- withdrawing substituents significantly influence the acid strength of both aliphatic as well as aromatic carboxylic acids.
Furthermore, unlike all other common aliphatic acids, formic acid uniquely possesses reducing properties and simultaneously does not display the typical reactions characteristic of the alkyl group.
Fehling Solution A and B respectively, are :

The value of \(\int_{-\frac{\pi}{2}}^{\frac{\pi}{2}}(\sin |x|+\cos |x|) d x\), is equal to:

Question based on the following passage:
P-Block elements are placed in group 13 to 18 in the periodic table. Group 15 is nitrogen family.
Nitrogen can react with hydrogen, oxygen, halogens etc. It shows multiple oxidation states in its various oxides i.e. \(N_2O, N_2O_3, N_2O_5\) etc. Important allotropic forms of phosphorus are white, red and black phosporus. Various compounds of phosphorus are phosphine, \(PCl_3, PCl_5\) and oxoacids of phosphorus. Oxidation states \(+1\) to \(+5\) are seen in various oxoacids of phosphorus. Group 17 elements are collectively known as halogens. Bond dissociation enthalpy of \(F_2\) is smaller than \(Cl_2\).
The gases present in group 18 are chemically unreactive, they form only few compounds. Neil Bartlett (in 1962) observed the reaction of a noble gas. Since then, many noble gas compounds have been synthesised.
Amongst all noble gases, only Xe can form large number of compounds because :
(A) Its size is similar to that of Pt
(B) Its \(IE_1\) is almost identical with that of \(O_2\)
(C) Xe is not inert
(D) Xe is very large in size
(E) It has great affinity with \(PtF _6^{-}\)
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The probability distribution of a random variable X is given below:

x	-5	-4	-3	-2	-1	0	1	2	3	4	5
P(X)	p	2p	3p	4p	5p	7p	8p	9p	10p	11p	12p

Choose the correct statement(s) for Wolff Kishner Reaction.
(A) The carbonyl group of aldehyde and ketone is reduced to CH\(_2\) group.
(B) Wolff Kishner Reaction involves potassium hydroxide and ethylene glycol
(C) The reaction is carried out at a low temperature.
(D) Hydrazine is used in this reaction.
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The value of \(\int_1^2 \frac{\sqrt{x}}{\sqrt{3-x}+\sqrt{x}} d x\) is:

Let \(\left|\begin{array}{cc}x & 2 \\ 18 & x\end{array}\right|=\left|\begin{array}{ll}-4 & -2 \\ -8 &-4\end{array}\right|\). Then :
(A) \(x=-4\)
(B) \(x=-6\)
(C) \(x=4\)
(D) \(x=6\)
Choose the correct answer from the options given below :