Arrange the following in the decreasing order of their magnetic moment values:
A. Sc (Z=21)
B. V (Z=23)
C. Mn (Z=25)
D. Fe (Z=26)
E. Ni (Z=28)
Choose the correct answer from the options given below:

Read the passage carefully and answer the questions
Ethers with the general formula \(C _n H _{2 n+2} O\) and functional group C-O-C may be divided as symmetrical and unsymmetrical.
Lower symmetrical ether may be obtained by the dehydration of alcohols at low temperatures in the presence of protic acids,
such as \(H _2 SO _4\) and \(H _3 PO _4\) whereas at high temperature intramolecular dehydration takes place.
Formation of ether from primary alcohols is also accompanied by the formation of small amount of alkenes.
Due to the steric hinderance, secondary and tertiary alcohols undergo elimination reaction rather than substitution reaction yielding alkene as major product. Ethers can also be obtained by heating alkyl halides with sodium or potassium alkoxides.
Substituted Ethers (secondary & tertiary) can also be prepared using this method.
If primary halides are replaced with secondary and tertiary halides, alkenes are the major products.
The major product in the following reaction is \(ROH + HOR \xrightarrow{ H _2 SO _4, 140^{\circ} C }\)

Which of the following complexes will show absorbance of light at the lowest wavelength?

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Replacement of a hydrogen atom in a hydrocarbon by an alkoxy or carboxyl group yields a class of compounds known as ethers. Ethers are classified as symmetrical or unsymmetrical on the basis of groups attached to the oxygen atoms. Diethyl ether, a symmetrical ether, has been widely used as an inhalation anesthetic. Ethers can be prepared by acid catalyzed intermolecular dehydration of alcohols and Williamson's synthesis. Acid catalyzed dehydration of alcohols is not generally preferred as it gives a mixture of elimination and substitution products. In Williamson's synthesis, an alkyl halide is allowed to react with sodium alkoxide. Ethers containing substituted Alkyl groups may also be prepared by this method. The C-O bond in ether is weakly polar and is cleaved under drastic conditions with excess of hydrogen halides. In electrophilic substitution, the alkoxy group deactivates the aromatic ring and directs the incoming group to ortho and para positions.
Which type of ether is anisole ?

Lustre, electrical and thermal conductivity of metals can be explained by the theory of :

The conductivity of an ionic solution depends on:
A. The nature of the electrolyte added
B. The Volume of the container
C. The size of the ions and their solvation
D. Pressure
E. Concentration of the electrolytes
Choose the correct answer from the options given below :

Read the Passage carefully and answer the Questions
Kinetic studies not only help us to determine the rate of a chemical reaction but also describe the conditions by which the reaction rates can be altered. The factors such as concentration, temperature, pressure and catalyst affect the rate of a reaction.
The speed of a reaction or the rate of a reaction can be defined as the change in concentration of a reactant or product in unit time.
Rate \(=k[A]^{\text {a }}[B]^{\text {y }}\)
Here \(k\) is the rate constant
\(x+y\) gives the overall order of a reaction, whereas \(x\) and \(y\) repreeent the order with respect to the reactants \(A\) and \(B\), respectively.
Table: Initial rate of formation of NO 2

S No.	Initial [NO]/mol L-1	Initial [O2]/mol L-1	Initial rate of formation of NO2/mol L-1s-1
1.	0.30	0.3	0.096
2.	0.60	0.3	0.384
3.	0.30	0.6	0.192
4.	0.60	0.6	0.768

Match List-I with List-II (Given that \(c\) is an arbitrary constant)

List-I	List-II
(A) \(\int \frac{d x}{\sqrt{a^2-x^2}}\)	(I) \(\log _e\left|x+\sqrt{x^2-a^2}\right|+c\)
(B) \(\int \sqrt{a^2-x^2} d x\)	(II) \(\sin ^{-1} \frac{x}{a}+c\)
(C) \(\int \sqrt{x^2-a^2} d x\)	(III) \(\frac{x}{2} \sqrt{a^2-x^2}+\frac{a^2}{2} \sin ^{-1} \frac{x}{a}+c\)
(D) \(\int \frac{d x}{\sqrt{x^2-a^2}}\)	(IV) \(\frac{x}{2} \sqrt{x^2-a^2}-\frac{a^2}{2} \log _e\left|x+\sqrt{x^2-a^2}\right|+c\)

Choose the correct answer from the options given below :

The magnetic flux ( \(\Phi\) ) is:

\(H_3 C-CH_2-CH_2-CH_2-CH=CH_2 \xrightarrow{HBr} A\)
A will be

Read the following passage carefully and answer the given questions. During anaerobic sludge digestion, bacteria produce a mixture of gases such as methane, hydrogen sulphide and carbon dioxide. These gases form biogas and can be used as source of energy as it is inflammable. The bioactive molecule, cyclosporin A, that is used as an immunosuppressive agent in organ-transplant patients, is produced by the fungus Trichoderma polysporum. You must have noticed that bottled fruit juices bought from the market are clearer as compared to those made at home. This is because the bottled juices are clarified by the use of pectinases and proteases. Statins produced by the yeast Monascus purpureus have been commercialised as blood-cholesterol lowering agents. It acts by competitively inhibiting the enzyme responsible for synthesis of cholesterol. The BOD test measures the rate of uptake of oxygen by microorganisms in a sample of water and thus, indirectly, BOD is a measure of the organic matter present in the water.
BOD is a measure of-

Answer the question on the basis of passage given below :
One of the notable features of the transition element is the great variety of oxidation states it may show in its compounds. The elements which give the greatest number of oxidation states occur in or near the middle of the series. Manganese, for example exhibits all the oxidation states from +2 to +7. The lesser number of oxidation states at the extreme ends is either due to losing or sharing of few electrons (Sc, Ti) or too many d electrons of higher valence. Early in the first series scandium (II) is virtually unknown and titanium (IV) which is more stable than Ti (III) or Ti (II). On the other end, the only oxidation state of zinc is \(+ 2\).
Oxidation state of scandium is

Predict the order of decreasing reactivity of the following compounds towards SN1 reaction.
(A) \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{Br}\)
(B) \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}\left(\mathrm{C}_6 \mathrm{H}_5\right) \mathrm{Br}\)
(C) \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}\left(\mathrm{CH}_3\right) \mathrm{Br}\)
(D) \(\mathrm{C}_6 \mathrm{H}_5 \mathrm{C}\left(\mathrm{CH}_3\right)\left(\mathrm{C}_6 \mathrm{H}_5\right) \mathrm{Br}\)