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CUET · CHEMISTRY · PYQ PAPER 2023

Answer the question on the basis of passage given below:
Aldehydes are generally more reactive than ketones in nucleophilic addition reactions due to steric and electronic reasons. Sterically, the presence of two relatively large substituents in ketones hinders the approach of nucleophile to carbonyl carbon more than aldehydes having only one such substituent Electronically aldehydes are more reactive than ketones because two alkyl groups reduce the elctrophilicity of the carbonyl more effectively than in former.
For preparation of phenylethanoic acid from benzyl alcohol, reagents required are
A. HBr
B. \(CO _2\)
C. \(K C N\)
D. \(\Delta / H_3 O^{+}\)
E. \(AgNO _3\)
Choose the correct answer from the options given below:

  1. A A, B and C only
  2. B A, C and D only
  3. C A, C and E only
  4. D A, B and E only
Verified Solution

Answer & Solution

Correct Answer

(B) A, C and D only

Step-by-step Solution

Detailed explanation

\(C_6H_5CH_2OH + HBr \rightarrow C_6H_5CH_2Br + H_2O\) \(C_6H_5CH_2Br + KCN \rightarrow C_6H_5CH_2CN + KBr\) \(C_6H_5CH_2CN \xrightarrow{H_3O^+ / \Delta} C_6H_5CH_2COOH + NH_3\) Reagents required: HBr (A), KCN (C), \(\Delta / H_3 O^{+}\) (D).
From CUET
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