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CUET · CHEMISTRY · PYQ PAPER 2023

Answer the question on basis of passage given below:
Transition metals form a large number of complexes or coordination compounds in which the metal atoms are bound to a number of anions or neutral molecules. The valence bond theory explain the formation, magnetic behaviour and geometrical shapes while the crystal field theory explains the effect of different crystal fields on the degeneracy of d-orbitals energies of the central metal atom/ion. This provides for the quantitative estimation of orbital separation energies, magnetic moments and spectral and stability parameters.

  1. A \(\left[ Ni \left( H _2 O \right)_6\right]^{2+} \ -p^3 d^2\)
  2. B \(\left[ CoF _6\right]^{3-}-s p^3 d^2\)
  3. C \(\left[ Cu \left( NH _3\right)_4\right]^{2+} \ldots d s p^2\)
  4. D \(\left[ MnCl _4\right]^{2-} d s p^2\)
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Correct Answer

(B) \(\left[ CoF _6\right]^{3-}-s p^3 d^2\)

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Detailed explanation

Co in \(\left[ CoF _6\right]^{3-}\) is \(+3\). \(Co^{3+}\) electronic configuration: \([Ar] 3d^6\). \(F^-\) is a weak field ligand, coordination number is 6. High spin octahedral complex, hybridization: \(sp^3d^2\).
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