CUET · CHEMISTRY · PYQ PAPER 2023
Answer the question on basis of passage given below :
P block elements are placed in groups 13 to 18 of the periodic table. Their valence shell electronic configuration is \(ns^2 np^{1-6}\). Group 16 of the p block elements are known as the group of chalcogens having \(ns^2 np^4\) as their general electronic configuration. They exhibit number of oxidation states but the stability of \(- 2\) oxidation state decreases down the group. They are sometimes also known as group of chalcogens as the name is derived from the Greek word for brass and points to the association of sulphur and its congeners with copper. Their ionisation enthalpy decreases down the group. Oxygen shows anomalous behaviour due to its small size and high electronegativity.
What will be the products formed in the following equation?
- A \(UF_4(g)\) and \(3UCl(g)\)
- B \(UF_6(g)\) and \(3ClF(g)\)
- C \(UF_4(g)\) and \(3ClF(g)\)
- D \(UF_6(g)\) and \(3UCl(g)\)
Answer & Solution
Correct Answer
(B) \(UF_6(g)\) and \(3ClF(g)\)
Step-by-step Solution
Detailed explanation
\(U(s) + 3ClF_3(g) \rightarrow UF_6(g) + 3ClF(g)\) Products: \(UF_6(g)\) and \(3ClF(g)\)
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- Answer the question on the basis of passage given below :
Aldehydes and ketones represent two essential classes of organic compounds
which are extensively used in the synthesis of a wide variety of other organic molecules.
Due to the inherent polarity of the central carbonyl group, these substances readily undergo nucleophilic addition reactions.
Broadly speaking, these addition reactions can be categorized into two types:
one in which simple addition of the nucleophilic reagent occurs across the \(> C = O\) bond, and the second type where the initial addition is subsequently followed by the elimination of a water molecule.
A variety of ammonia derivatives, including hydroxylamine, hydrazine, phenylhydrazine,
2, 4-dinitroplhenylhdrazine, and semicarbagide, all belong to this second category of reactions.
These specific derivatives are fundamentally used for the identification and definitive characterization of aldehydes and ketones. Significantly, both types of nucleophilic addition reactions are strongly influenced by both steric and electronic factors.
As a general rule, aliphatic aldehydes exhibit higher reactivity compared to aromatic aldehydes.
The aliphatic aldehydes demonstrate the ability to reduce both Fehling's solution and Tollen's reagent, whereas aromatic aldehydes are limited to reducing only Tollen's reagent.
In a similar manner to aldehydes, aromatic ketones are observed to be less reactive than aliphatic ketones towards all nucleophilic addition reactions.
In a separate context, phenols and carboxylic acids both exhibit acidic properties in nature.
Both classes of compounds readily dissolve in NaOH solution and cause blue litmus to turn red.
However, carboxylic acids stand out as much stronger acids than phenols and thus can decompose sodium bicarbonate \(\left( NaHCO _3\right)\) with the distinct evolution of \(CO _2\) gas, a reaction which phenols do not undergo.
It is important to note that both electron- donating and electron- withdrawing substituents significantly influence the acid strength of both aliphatic as well as aromatic carboxylic acids.
Furthermore, unlike all other common aliphatic acids, formic acid uniquely possesses reducing properties and simultaneously does not display the typical reactions characteristic of the alkyl group.
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When a ligand is bound to a metal ion through a single donor atom, it is said to be a unidentate ligand but when it bind through two donor atoms, then it is said to be didentate ligand and when several donor atoms are present in a single ligand, it is said to be a polydentate ligand. When a dior polydentate ligand uses its two or more donor atoms simultaneously to bind a single metal ion, it is said to be a chelate ligand. The number of such ligating groups is called the denticity of the ligand. ligand which has two different donor atoms and either of the two ligetes in the complex is called ambidentate ligands. The number of ligand donor atoms to which the metal is directly bonded, is called coordination number of the metal ion in the complex. Complexes in which a metal is bound to only one kind of donor groups are known as homoleptic and in which a metal is bound to more than one kind of donor groups are known as heteroleptic complexes.
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