Acylation of aniline with acetic anhydride gives :

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Production of electricity by thermal plants is not very efficient method. It is now possible to make cells in which reactants are fed continuously to the electrodes and products are also removed continuously. One of the most successful fuel cells is hydrogen fuel cell.
Hydrogen fuel cell is an :

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Amines are classified as primary \(\left(1^{\circ}\right)\), secondary \(\left(2^{\circ}\right)\) and tertiary \(\left(3^{\circ}\right)\) depending upon the number of hydrogen atoms replaced by alkyl or aryl groups in ammonia molecules. Aliphatic amines are a stronger bases due to \(+I\) effect of an alkyl groups. Intermolecular hydrogen bonding in primary and secondary amines affects the boiling points of amines. The intermolecular association is more in primary amines than in secondary amines as there are more number of hydrogen atoms available for hydrogen bond formation. Nitro compounds are reduced to amines by passing hydrogen gas in the presence of finely divided nickel, palladium or platinum and also by reduction with metals in an acidic medium. Gabriel synthesis is used for the preparation of primary amines. Primary amines react with nitrous acid to give unstable diazonium-salts which can be used to synthesize a variety of compounds.
Identify the amine possessing least basic strength:

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Lyophobic sols like those of metals (Au, Ag, etc) are unstable and are easily precipitated by addition of electrolytes. However, it is observed that the addition of certain lyophilic colloids like gums, soaps, gelatine, etc. to lyophobic colloids (like a metal sol) render lyophobic colloids difficult to coagulate by the addition of electrolytes. The process is known as 'protection' and the lyophilic colloid. colloids are termed as Protective colloids. It is believed that the protective action of the lyophilic colloids is due to the covering up of the particles of the lyophobic colloid by those of the lyophilic Evidenty, smaller the gold number of a protective colloid, the greater is its protective action.
Critical micelle concentration of soap solutions lie in the range of :

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The resistance (\(R\) ) of an object is given by the expression \(R=\rho \frac{l}{A}\).
The inverse of \(R\) is called conductance and the inverse of \(\rho\) is called conductivity or specific conductance represented by \(\kappa\).
The conductivity depends upon the nature of the material (insulator, semiconductor or conductor) and the temperature of the substance.
Similarly, the conductance due to the ions present in the solution (ionic conductance) depends upon the nature of the electrolyte, size of ions, the nature of the solvent and the temperature.
Molar conductivity ( \(\Lambda_m\) ) of a solution at a given concentration is the conductance of volume \(V\) containing one mole of electrolyte kept between two electrodes of area \(A\) and unit distance apart.
It is given by the expression \(\Lambda_m=\kappa V\).
Molar conductivity increases with decrease in concentration and when concentration approaches zero, it is called limiting molar conductivity.
The decrease is linear for a strong electrolyte. However, for a weak electrolyte the change is gradual at higher concentrations and sharp near zero concentration.
Using limiting molar conductivity values of strong electrolytes we can calculate the limiting molar conductivity of weak electrolytes using Kohlrausch law of independent migration of ions.
From molar conductivity and limiting molar conductivity we can determine the degree of dissociation \(\left(\frac{\Lambda_m}{\Lambda_m^0}\right)\) and the ionization constant of a weak acid.
SI units of conductance and conductivity, respectively, are ___________

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Werner in 1898, propounded his theory of coordination compounds. In coordination compounds metals show two types of linkages (valences)-primary and secondary. The primary valences are normally ionisable and are satisfied by negative ions. The secondary valences are non-ionisable. These are satisfied by neutral molecules or negative ions. The secondary valence is equal to the coordination number and is fixed for a metal. The ions or group bound by the secondary linkages to the metal have characteristic spatial arrangements corresponding to the different coordination numbers. Both double salts as well as complexes are formed by the combination of two or more stable compounds in stoichiometric ratio. However, they differ in the fact that double salts such as carnallite, Mohr's salt, potash alum etc. dissociate into simple ions completely when dissolved in water. But complex ions do not dissociate completely into simple ions.
Which of the following statement is correct as per Werner theory?

Which of the following compounds will not undergo aldol condensation?

Match List - I with List - II.

List - I (Electronic Device)	List - II (Application)
(A) Zener diode	(I) Rectifier
(B) Capacitor	(II) Amplifier
(C) Transistor	(III) Voltage regulator
(D) p-n junction diode	(IV) Filter circuit

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Double fertilisation is unique to:

Resonant frequency of a LCR series circuit is 16 kHz. If the capacitance is increased to 16 times, then the new resonant frequency will become

The construction of the first recombinant DNA emerged from linking a gene encoding antibiotic resistance with a native plasmid of __________.

Let \(A\) be a square matrix of order \(3 \times 3\), then \(|K A|\) is equal to :

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Biofertilisers
Biofertilisers are organisms that enrich the nutrient quality of the soil and their main sources are bacteria, fungi and cyanobacteria. You have studied about the nodules on the roots of leguminous plants formed by the symbiotic association of Rhizobium. These bacteria can fix atmospheric nitrogen into organic forms. Other bacteria can also fix atmospheric nitrogen while free-living in the soil (examples Azospirillum and Azotobacter). Fungi are also known to form symbiotic associations with plants (mycorrhiza). Many members of the genus Glomus form mycorrhiza. Plants having such associations show other benefits also, such as resistance to root-borne pathogens, tolerance to salinity and drought, and an overall increase in plant growth and development. Cyanobacteria are autotrophic microbes widely distributed in aquatic and terrestrial environments many of which can fix atmospheric nitrogen, e.g. Anabaena, Nostoc, Oscillatoria, etc. In paddy fields, cyanobacteria serve as an important biofertiliser. Blue green algae also add organic matter in to the soil and increase its fertility. Currently, in our country, a number of biofertilisers are available commercially in the market and farmers use these regularly in their fields to replenish soil nutrients and to reduce dependence on chemical fertilisers.
Choose the free living, nitrogen-fixing bacteria from the following.