A first order reaction is found to have rate constant \(k=3.0 \times 10^{-1} \mathrm{~s}^{-1}\). The half-life of the reaction will be:

Arrange the following compounds in increasing order of their solubility in water :
(A) n-butanol
(B) Butan-1-amine
(C) Methanamine
(D) Aniline

Which of the following pairs of solutions are isotonic?

Answer the question on basis of passage given below :
Look at the following chemical reactions and answer the following question :
(A) \(C_7H_8 \xrightarrow{\text{Conc. HNO}_3, 0^\circ C}
(B) \xrightarrow{Sn/HCl}
(C) \xrightarrow{NaNO_2/H_3O^+}
(D) \xrightarrow{H_2O, Heat}(E)\)
(E) \(CH_3I \xrightarrow{KMnO_4/H^+}
(F) \xrightarrow{H_3O^+}
(G) \xrightarrow{NaOH} (H)\)
Which are water soluble ?

Read the passage carefully and answer the Questions
Werner in 1898, propounded his theory of coordination compounds. In coordination compounds metals show two types of linkages (valences)-primary and secondary. The primary valences are normally ionisable and are satisfied by negative ions. The secondary valences are non-ionisable. These are satisfied by neutral molecules or negative ions. The secondary valence is equal to the coordination number and is fixed for a metal. The ions or group bound by the secondary linkages to the metal have characteristic spatial arrangements corresponding to the different coordination numbers. Both double salts as well as complexes are formed by the combination of two or more stable compounds in stoichiometric ratio. However, they differ in the fact that double salts such as carnallite, Mohr's salt, potash alum etc. dissociate into simple ions completely when dissolved in water. But complex ions do not dissociate completely into simple ions.
Which of the following statement is correct as per Werner theory?

In case of phosphorus, \(\text{PCl}_3\) and \(\text{PCl}_5\) are possible while nitrogen only forms \(\text{NCl}_3\), and not \(\text{NCl}_5\). This due to :

Correct IUPAC name of
CH3-CH2-CH=CH-CO-H
is:

A gaussian surface encloses three point charges \( q_1 = -14 \text{ nC}, q_2 = 78.85 \text{ nC} \) and \( q_3 = -56 \text{ nC} \). The electric flux for the gaussian surface due to these charges is

Biogas is mixture of:

In the following differential equation \(\frac{d^2 y}{d x^2}+x\left(\frac{d y}{d x}\right)^2=2 x^2 \log \left(\frac{d^2 y}{d x^2}\right)\) order and degree is:

The spermatids are transformed into spermatozoa by the process called as

The inequality \(\frac{5 x-2}{3}-\frac{7 x-3}{5}>\frac{x}{4}\) holds when

The properties which depend on the number of solute particles irrespective of their nature relative to the total number of particles in the solution are called colligative properties. These are relative lowering of vapour pressure of the solvent, depression of freesing point of the solvent, elevation of boiling point of the solvent and osmotic pressure of the solution. All of these properties help in calculating the observed molar mass of the solute.
Determination of osmotic pressure is considered best for the determination of molecular mass of the solute.
The binary liquid mixtures which show negative deviation from Raoult's law are :
(A) n-hexane and n-heptone
(B) phenol and acetone
(C) ethanol and acetone
(D) chloroform and acetone
(E) benzene and toluene
Choose the correct answer from the options given below :