CUET · BIOLOGY · PYQ PAPER 2023
Match List - I with List - II.
| List-I | List-II |
| (A) Cuckoo lays egg in crow’s nest | (IV) Brood parasitism |
| (B) Orchid grows in mango tree | (I) Commensalism |
| (C) Ticks live on skin of dogs | (II) Parasitism |
| (D) Species of Wasp and fig species | (III) Mutualism |
Choose the correct answer from the options given below :
- A (A)-(I), (B)-(IV), (C)-(II), (D)-(III)
- B (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
- C (A)-(IV), (B)-(I), (C)-(III), (D)-(II)
- D (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
Answer & Solution
Correct Answer
(B) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
Step-by-step Solution
Detailed explanation
(A)-(IV), (B)-(I), (C)-(II), (D)-(III)
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Carboxylic acids are weaker than mineral acids, but they are stronger acids than alcohols and many simple phenols (\(\text{pKa}\) is ~ 16 for ethanol and 10 for phenol). The higher acidity of carboxylic acids as compared to phenols can be understood similarly. The conjugate base of carboxylic acid, a carboxylate ion, is stabilised by two equivalent resonance structures in which the negative charge is at the more electronegative oxygen atom. The conjugate base of phenol, a phenoxide ion, has non-equivalent resonance structures in which the negative charge is at the less electronegative carbon atom. Further, the negative charge is delocalised over two electronegative oxygen atoms in carboxylate ion whereas it is less effectively delocalised over one oxygen atom and less electronegative carbon atoms in phenoxide ion. Thus, the carboxylate ion is more estabilised than phenoxide ion, so carboxylic acids are more acidic than phenols.
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