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COMEDK · Chemistry · 24. Coordination Compounds

Which one of the following structures in Column I does not have the correct IUPAC name as given in Column II.
\(\begin{array}{|c|l|l|} \hline \text { S.No. } & \text { Structure } & \text { IUPAC name. } \\ \hline \text { A } & {\left[\mathrm{CoBr} r_2(\mathrm{en})_2\right] \mathrm{Cl}} & \text { Dibromidodi-( ethan-1, 2 - diamine)cobalt (III) chloride } \\ \hline \text { B } & \mathrm{Na}\left[\mathrm{PtBrCl}\left(\mathrm{NO}_2\right)\left(\mathrm{NH}_3\right)\right] & \text { Sodium amminebromidochloridonitrito- N- palatinate(II) } \\ \hline \text { C } & {\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_2\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}\right] \mathrm{SO}_4} & \text { Tetraamminediaquachloridochromium (III) sulphate. } \\ \hline \text { D } & {\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4\right]\left[\mathrm{PtCl}_4\right]} & \text { Tetraammineplatinum (II) tetrachloridoplatinate (II) } \\ \hline \end{array}\)

  1. A A
  2. B C
  3. C B
  4. D D
Verified Solution

Answer & Solution

Correct Answer

(A) A

Step-by-step Solution

Detailed explanation

In option A, the complex is \(\left[\mathrm{CoBr}_{2}(\mathrm{en})_{2}\right]\mathrm{Cl}\). The IUPAC name is dibromidobis(ethane-1,2-diamine)cobalt(III) chloride. The prefix 'di' is used for simple ligands, but for ligands like ethane-1,2-diamine which already contain a…