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COMEDK · Chemistry · 17. Solutions

Which of the following solutions will exhibit highest boiling point?

  1. A \(0.01 \mathrm{M} \mathrm{Na}_{2} \mathrm{SO}_{4}(a q)\)
  2. B \(0.01 \mathrm{M} \mathrm{KNO}_{3}(a q)\)
  3. C \(0.015 \mathrm{M}\) urea \((a q)\)
  4. D \(0.015 \mathrm{M}\) glucose \((a q)\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(0.01 \mathrm{M} \mathrm{Na}_{2} \mathrm{SO}_{4}(a q)\)

Step-by-step Solution

Detailed explanation

For, assume complete dissociation For \(\mathrm{Na}_{2} \mathrm{SO}_{4} ; \quad i=3, m=0.01\) \[ \begin{aligned} &\Delta T_{b}=i K_{b} m \\ &\Delta T_{b}=3 \times K_{b} \times 0.01=0.03 K_{b} \end{aligned} \] For, 0.01 M \(\mathrm{KNO}_{3}\);…