COMEDK · Chemistry · 23. d and f Block Elements

Which of the following has the maximum number of unpaired \(d\)-electrons?

A \(\mathrm{Zn}^{2+}\)
B \(\mathrm{Fe}^{2+}\)
C \(\mathrm{Ni}^{3+}\)
D \(\mathrm{Cu}^{+}\)

Verified Solution

Answer & Solution

Correct Answer

(B) \(\mathrm{Fe}^{2+}\)

Step-by-step Solution

Detailed explanation

The electronic configuration of \(\begin{aligned} \mathrm{Fe}(26) &=1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{6} 4 s^{2} \\ \mathrm{Fe} &=1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{6} 4 s^{0} \end{aligned}\) It has four unpaired electrons.

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

Match the reactions in List I with the final products formed as given in List II.

List I		List II
W	\(\text{C}_6\text{H}_5\text{CH}_3 \xrightarrow{\large{(i)\text{CrO}_3 + (\text{CH}_3\text{CO})_2\text{O};\ (ii)\text{H}_2\text{O} + heat}}\)	P	\(\text{R}_2\text{CO}\)
X	\(\text{RCOOC}_2\text{H}_5 \xrightarrow{\large{(i)\text{DIBAL-H};\ (ii)\text{H}_2\text{O}}}\)	Q	\(\text{C}_6\text{H}_5\text{COCH}_3\)
Y	\(\text{RCN} \xrightarrow{\large{(i)\text{R-Mg-X /dry ether};\ (ii)\text{H}_3\text{O}^+}}\)	R	\(\text{C}_6\text{H}_5\text{CHO}\)
Z	\(\text{C}_6\text{H}_5\text{COCl} + (\text{CH}_3)_2\text{Cd in dry ether} \rightarrow\)	S	\(\text{RCHO}\)

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