COMEDK · Chemistry · 22. p Block Elements (Group 15, 16, 17 & 18)
Which among the following will not liberate nitrogen on reaction with nitrous acid?
- A dimethylamine
- B 2-aminopropane
- C ethylamine
- D methylamine
Answer & Solution
Correct Answer
(A) dimethylamine
Step-by-step Solution
Detailed explanation
Nitrous acid (\(HNO_{2}\)) reacts with primary aliphatic amines (\(R-NH_{2}\)) to form unstable diazonium salts, which decompose to evolve nitrogen gas (\(N_{2}\)) and form alcohols. Ethylamine (\(CH_{3}CH_{2}NH_{2}\)), methylamine (\(CH_{3}NH_{2}\)), and 2-aminopropane…
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