COMEDK · Chemistry · 24. Coordination Compounds

The type of hybridisation and the spin only magnetic moment for the complex \([\mathrm{Ni}(\mathrm{CO})_4]\) are respectively:

A \(\mathrm{dsp}^2, \sqrt{8} \mathrm{~BM}\)
B \(\mathrm{dsp}^2\), zero
C \(\mathrm{sp}^3, \sqrt{8} \mathrm{~BM}\)
D \(\mathrm{sp}^3\), zero

Verified Solution

Answer & Solution

Correct Answer

(D) \(\mathrm{sp}^3\), zero

Step-by-step Solution

Detailed explanation

The central metal atom is Nickel (Ni) with atomic number 28. The electronic configuration of Ni is \([Ar] 3d^{8} 4s^{2}\). In the complex \([Ni(CO)_{4}]\), the oxidation state of Ni is 0, as CO is a neutral ligand. The configuration remains \([Ar] 3d^{8} 4s^{2}\). CO is a strong…

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

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