COMEDK · Chemistry · 23. d and f Block Elements

The Lanthanoid ion which would form coloured compounds is -------------.
Atomic numbers: \(\mathrm{Yb}=70, \quad \mathrm{Lu}=71, \mathrm{Pr}=59, \quad \mathrm{La}=57\)

A \(\operatorname{Pr}^{3+}\)
B \(L a^{3+}\)
C \(Y b^{2+}\)
D \(L u^{3+}\)

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Answer & Solution

Correct Answer

(A) \(\operatorname{Pr}^{3+}\)

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Detailed explanation

Lanthanoid ions exhibit colour due to \(f-f\) electronic transitions. Ions with partially filled \(f\)-orbitals (\(f^1\) to \(f^{13}\)) are coloured, while ions with \(f^0\) or \(f^{14}\) configurations are colourless. Electronic configurations of the given ions are: 1.…

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

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The Lanthanoid ion which would form coloured compounds is -------------.Atomic numbers: \(\mathrm{Yb}=70, \quad \mathrm{Lu}=71, \mathrm{Pr}=59, \quad \mathrm{La}=57\)

Step-by-step Solution

The Lanthanoid ion which would form coloured compounds is -------------.
Atomic numbers: \(\mathrm{Yb}=70, \quad \mathrm{Lu}=71, \mathrm{Pr}=59, \quad \mathrm{La}=57\)