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COMEDK · Chemistry · 18. Electrochemistry

The \(\mathrm{E}^{\circ}\) values of \(\mathrm{A} . \mathrm{B}\) and \(\mathrm{C}\) are given. Which element/(s) is/(are) good for coating the surface of iron to prevent corrosion?
Given: \([\mathrm{E}_{\mathrm{Fe}^{2+} / \mathrm{Fe}}^0=-0.44 \mathrm{~V} ; \quad \mathrm{E}_{\mathrm{A}^{2+} / \mathrm{A}}^0=-2.37 \mathrm{~V} ; \quad \mathrm{E}_{\mathrm{B}^{2+} / \mathrm{B}}^0=-0.15 \mathrm{~V} ; \quad \mathrm{E}_{\mathrm{C}^{2+} / \mathrm{C}}^0=+0.34 \mathrm{~V}]\)

  1. A Element C only
  2. B Elements B and C
  3. C Element A only
  4. D Element B only
Verified Solution

Answer & Solution

Correct Answer

(C) Element A only

Step-by-step Solution

Detailed explanation

To prevent the corrosion of iron, the metal used for coating must act as a sacrificial anode. This means the coating metal must have a more negative standard reduction potential than that of iron (\(E^{\circ}_{Fe^{2+}/Fe} = -0.44 \text{ V}\)). Comparing the given standard…