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COMEDK · Chemistry · 14. Hydrocarbons

The decreasing order of reactivity towards electrophilic substitution of the following compounds is


  1. A \(1>3>4>2\)
  2. B \(4>1>3>2\)
  3. C \(4>1>2>3\)
  4. D \(1>4>3>2\)
Verified Solution

Answer & Solution

Correct Answer

(C) \(4>1>2>3\)

Step-by-step Solution

Detailed explanation

Due to \(+I\)-effect of \(-\mathrm{CH}_{3}\) group (4) has higher electron density, than benzene (1). Due to strong \(-I\)-effect of - Cl group and strong \(-I\) and \(-M\)-effect of \(-\mathrm{NO}_{2}\) group, both (2) and (3) have lower electron density, than benzene (l). As -…