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COMEDK · Chemistry · 25. Haloalkanes and Haloarenes

\(t\)-butyl chloride preferably undergo hydrolysis by

  1. A any of (a) and (b)
  2. B \(\mathrm{S}_{\mathrm{N}} 1\) mechanism
  3. C None of the above
  4. D \(\mathrm{S}_{\mathrm{N}} 2\) mechanism
Verified Solution

Answer & Solution

Correct Answer

(B) \(\mathrm{S}_{\mathrm{N}} 1\) mechanism

Step-by-step Solution

Detailed explanation

\(t\)-butyl chloride is a tertiary alkyl halide, represented as \((CH_{3})_{3}CCl\). In nucleophilic substitution reactions, tertiary alkyl halides are highly sterically hindered, which prevents the approach of a nucleophile from the backside, making the…