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COMEDK · Chemistry · 13. General Organic Chemistry

Presence of peroxides in old stocks of ethers can be tested by first treating them with \(\mathrm{Fe}^{2+}\) ions and then adding an aqueous solution of

  1. A KCNS
  2. B \(\mathrm{HgCl}_2\)
  3. C \(\mathrm{SnCl}_2\)
  4. D KI
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Answer & Solution

Correct Answer

(A) KCNS

Step-by-step Solution

Detailed explanation

Peroxides, if present, in old stocks of ethers oxidise \(\mathrm{Fe}^{2+}\) to \(\mathrm{Fe}^{3+}\) ions which then combines with KCNS to form blood red colouration due to formation of ferric sulphocyanide.…
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