COMEDK · Chemistry · 27. Aldehydes and Ketones
Match the reactions in List I with the final products formed as given in List II.
| List I | List II | ||
|---|---|---|---|
| W | \(\text{C}_6\text{H}_5\text{CH}_3 \xrightarrow{\large{(i)\text{CrO}_3 + (\text{CH}_3\text{CO})_2\text{O};\ (ii)\text{H}_2\text{O} + heat}}\) | P | \(\text{R}_2\text{CO}\) |
| X | \(\text{RCOOC}_2\text{H}_5 \xrightarrow{\large{(i)\text{DIBAL-H};\ (ii)\text{H}_2\text{O}}}\) | Q | \(\text{C}_6\text{H}_5\text{COCH}_3\) |
| Y | \(\text{RCN} \xrightarrow{\large{(i)\text{R-Mg-X /dry ether};\ (ii)\text{H}_3\text{O}^+}}\) | R | \(\text{C}_6\text{H}_5\text{CHO}\) |
| Z | \(\text{C}_6\text{H}_5\text{COCl} + (\text{CH}_3)_2\text{Cd in dry ether} \rightarrow\) | S | \(\text{RCHO}\) |
- A W - R X - P Y - Q Z - S
- B W - Q X - P Y - S Z - R
- C W - S X - R Y - Q Z - P
- D W - R X - S Y - P Z - Q
Answer & Solution
Correct Answer
(D) W - R X - S Y - P Z - Q
Step-by-step Solution
Detailed explanation
Reaction W: Toluene (\(\text{C}_6\text{H}_5\text{CH}_3\)) reacts with chromic oxide (\(\text{CrO}_3\)) in acetic anhydride to form benzylidene diacetate, which on hydrolysis yields benzaldehyde (\(\text{C}_6\text{H}_5\text{CHO}\)). Thus, W matches with R. Reaction X: Esters…
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