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COMEDK · Chemistry · 26. Alcohols Phenols and Ethers

Match the reaction in Column I with the major product formed given in Column II.
\(\begin{array}{|l|l|l|} \hline & \text { Column I- Reaction/conditions } & & \text { Column II- Product } \\ \hline A & \mathrm{C}_6 \mathrm{H}_6 \xrightarrow[\substack{\text{(ii) NaOH} \\ \text{(iii) H^+}}]{\text{(i) Oleum}} & P & \text { Pentan-2-ol. } \\ \hline B & \text{Butanal } \xrightarrow[\text{(ii) } \mathrm{H}^+]{\text{(i) } \text{MeMgBr/ dry ether}} & Q & \text { 2-Hydroxybenzoic acid. } \\ \hline C & \text {2-Methylpropene } \xrightarrow[\text { (ii) } \mathrm{H}_2 \mathrm{O}_2 / \mathrm{NaOH}]{\text { (i) } \mathrm{B}_2 \mathrm{H}_6} & R & \text { Phenol } \\ \hline D & \text{Phenol } \xrightarrow[\text { (ii) } \mathrm{CO}_2, 400 \mathrm{~K}, 7 \mathrm{~atm} .]{\text { (i) } \mathrm{NaOH}} & S & \text { 2-Methylpropan-1-0 I } \\ \hline \end{array}\)

  1. A \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q}\)
  2. B \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}\)
  3. C \(\mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{R}\)
  4. D \(\mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{R}\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q}\)

Step-by-step Solution

Detailed explanation

Reaction A: Benzene reacts with oleum to form benzenesulfonic acid, which upon fusion with NaOH followed by acidification yields phenol. Thus, A = R. Reaction B: Butanal (\(CH_3CH_2CH_2CHO\)) reacts with methylmagnesium bromide (\(MeMgBr\)) followed by acidic workup to form a…