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COMEDK · Chemistry · 25. Haloalkanes and Haloarenes

Match the names of reactions given in Column I with the appropriate reactions given in Column II.

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No.Name of reactionNo.Equations representing reactions
ASandmeyerP\(2C_6H_5Cl + Na\) (dry ether) \(\to\) Diphenyl
BFittigQ\(CH_3 - CHBr - CH_3 + AgF \to CH_3 - CHF - CH_3 + AgBr\)
CSwartsR\(CH_3 - CH_2 - Br + NaI\) (Acetone) \(\to CH_3 - CH_2 - I + NaBr\)
DFinkelsteinS\(C_6H_5N_2^+ Cl^- + Cu_2Br_2/HBr \to C_6H_5Br + N_2\)

  1. A \(\mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{P}\)
  2. B \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{R}\)
  3. C \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}\)
  4. D \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{R}\)

Step-by-step Solution

Detailed explanation

Sandmeyer reaction involves the conversion of diazonium salts to aryl halides using copper(I) salts. This corresponds to reaction (S):…