COMEDK · Chemistry · 25. Haloalkanes and Haloarenes
Match the names of reactions given in Column I with the appropriate reactions given in Column II.
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| No. | Name of reaction | No. | Equations representing reactions |
|---|---|---|---|
| A | Sandmeyer | P | \(2C_6H_5Cl + Na\) (dry ether) \(\to\) Diphenyl |
| B | Fittig | Q | \(CH_3 - CHBr - CH_3 + AgF \to CH_3 - CHF - CH_3 + AgBr\) |
| C | Swarts | R | \(CH_3 - CH_2 - Br + NaI\) (Acetone) \(\to CH_3 - CH_2 - I + NaBr\) |
| D | Finkelstein | S | \(C_6H_5N_2^+ Cl^- + Cu_2Br_2/HBr \to C_6H_5Br + N_2\) |
- A \(\mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{P}\)
- B \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{R}\)
- C \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}\)
- D \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q}\)
Answer & Solution
Correct Answer
(B) \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{R}\)
Step-by-step Solution
Detailed explanation
Sandmeyer reaction involves the conversion of diazonium salts to aryl halides using copper(I) salts. This corresponds to reaction (S):…
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