COMEDK · Chemistry · 23. d and f Block Elements
Match the compounds given in Column I with their characteristic features listed in Column II
| No. | Column I | No. | Column II |
|---|---|---|---|
| A | \(La(OH)_3\) | P | Acidic in nature |
| B | \(Mn_2O_7\) | Q | Least basic |
| C | \(Lu(OH)_3\) | R | Interstitial compound |
| D | \(Fe_3H\) | S | Most basic |
- A \(\begin{array}{llll}
\mathrm{A}=\mathrm{Q} & \mathrm{B}=\mathrm{P} & \mathrm{C}=\mathrm{S} & \mathrm{D}=\mathrm{R}
\end{array}\) - B \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{R}\)
- C \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}\)
- D \(\begin{array}{llll}
\mathrm{A}=\mathrm{R} & \mathrm{B}=\mathrm{P} & \mathrm{C}=\mathrm{S} & \mathrm{D}=\mathrm{Q}
\end{array}\)
Answer & Solution
Correct Answer
(B) \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{R}\)
Step-by-step Solution
Detailed explanation
The basicity of lanthanoid hydroxides \(\mathrm{Ln}(\mathrm{OH})_3\) decreases as the ionic radius of the lanthanoid ion \(\mathrm{Ln}^{3+}\) decreases due to lanthanoid contraction. \(\mathrm{La}^{3+}\) has the largest ionic radius, making \(\mathrm{La}(\mathrm{OH})_3\) the…
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