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COMEDK · Chemistry · 7. Chemical Equilibrium

In which one of the following equilibria, pressure has no effect

  1. A \(\mathrm{PCl}_{5} \rightleftharpoons \mathrm{PCl}_{3}+\mathrm{Cl}_{2}\)
  2. B \(2 \mathrm{NH}_{3} \longrightarrow \mathrm{N}_{2}+3 \mathrm{H}_{2}\)
  3. C \(2 \mathrm{SO}_{2}+\mathrm{O}_{2} \rightleftharpoons 2 \mathrm{SO}_{3}\)
  4. D \(\mathrm{N}_{2}+\mathrm{O}_{2} \rightleftharpoons 2 \mathrm{NO}\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(\mathrm{N}_{2}+\mathrm{O}_{2} \rightleftharpoons 2 \mathrm{NO}\)

Step-by-step Solution

Detailed explanation

When \(\Delta n_{g}\) i.e. difference in gaseous moles of product and reactant is zero, then pressure has no effect and it is equilibrium point for reaction.…