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COMEDK · Chemistry · 25. Haloalkanes and Haloarenes

Identify the product formed when the following reaction occurs.


?

  1. A 2, 4-Dichloroethylbenzene.
  2. B 1, 2-Dichloro-1-phenylethane.
  3. C 1, 1-Dichloro-1-phenylethane.
  4. D 2,3-Dichloroethylbenzene.
Verified Solution

Answer & Solution

Correct Answer

(C) 1, 1-Dichloro-1-phenylethane.

Step-by-step Solution

Detailed explanation

The reaction of ethylbenzene with excess \(Cl_2\) in the presence of \(hv\) (ultraviolet light) is a free radical substitution reaction. The reaction occurs at the benzylic position because the resulting benzylic radical is resonance-stabilized by the benzene ring. The first…