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COMEDK · Chemistry · 23. d and f Block Elements

Identify the correct statement from the following.

  1. A \(\mathrm{Cr}(\mathrm{VI})\) is more stable than \(\mathrm{W}(\mathrm{VI})\) and hence acts as a good oxidising agent
  2. B Interstitial compounds of transition metals have lower melting points than that of pure transition metals and their compounds are chemically reactive
  3. C Cerium is a lanthanoid metal which exists in a stable oxidation state of +4 , besides exhibiting an oxidation state of +3
  4. D The green manganate ion shows diamagnetic nature but the permanganate ion exhibits paramagnetic nature
Verified Solution

Answer & Solution

Correct Answer

(C) Cerium is a lanthanoid metal which exists in a stable oxidation state of +4 , besides exhibiting an oxidation state of +3

Step-by-step Solution

Detailed explanation

Correct answer: (3) (1) Incorrect: Higher oxidation states become more stable down the group, so W(VI) is more stable than Cr(VI). Cr(VI) is less stable and hence acts as a strong oxidising agent. (2) Incorrect: Interstitial compounds have higher melting points than pure metals…