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COMEDK · Chemistry · 19. Chemical Kinetics

For a given reaction, ,\(\mathrm{X}(\mathrm{g})+\mathrm{Y}(\mathrm{g} \rightarrow \mathrm{Z}(\mathrm{g})\), the order of reaction with respect to \(\mathrm{X}\) and \(\mathrm{Y}\) are \(\mathrm{m}\) and \(\mathrm{n}\) respectively. If the concentration of \(\mathrm{X}\) is tripled and that of \(\mathrm{Y}\) is decreased to one third, what is the ratio between the new rate to the original rate of the reaction?

  1. A \(3^{(n-m)}\)
  2. B \((m+n)\)
  3. C \(\dfrac{1}{3^{(m+n)}}\)
  4. D \(3^{(m-n)}\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(3^{(m-n)}\)

Step-by-step Solution

Detailed explanation

The rate law for the reaction \(\mathrm{X}(\mathrm{g}) + \mathrm{Y}(\mathrm{g}) \rightarrow \mathrm{Z}(\mathrm{g})\) is given by \(r_1 = k[X]^m [Y]^n\). When the concentration of \(\mathrm{X}\) is tripled, \([X]' = 3[X]\). When the concentration of \(\mathrm{Y}\) is decreased to…
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