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COMEDK · Chemistry · 23. d and f Block Elements

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\(\begin{array}{|l|l|l|l|} \hline \text{A} & \mathrm{Cr}_2 \mathrm{O}_7^{2-} & \mathrm{P} & \text{is predominantly a basic compound.} \\ \hline \text{B} & \mathrm{FeCr}_2 \mathrm{O}_4 & \mathrm{Q} & \text{is predominantly an acidic compound.} \\ \hline \text{C} & \mathrm{CrO}_3 & \mathrm{R} & \text{forms yellow chromate on reaction with } \mathrm{Na}_2 \mathrm{CO}_3 \text{ in air.} \\ \hline \text{D} & \mathrm{CrO} & \mathrm{S} & \text{is interconvertible with } \mathrm{MO}_4^{2-} \text{ depending on the pH of the medium.} \\ \hline \end{array}\)

  1. A \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q}\)
  2. B \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{Q} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{P}\)
  3. C \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}\)
  4. D \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q}\)
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(C) \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}\)

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The dichromate ion \(\mathrm{Cr}_2 \mathrm{O}_7^{2-}\) exists in equilibrium with the chromate ion \(\mathrm{CrO}_4^{2-}\) depending on the pH of the medium, where…