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COMEDK · Chemistry · 23. d and f Block Elements

Consider the following statements in respect of lanthanides, which of the statements are incorrect?
(i) \(\mathrm{La}(\mathrm{OH})_3\) is least basic among the hydroxides of lanthanides
(ii) The lanthanide ions \(\mathrm{Yb}^{2+}, \mathrm{Lu}^{3+}\) and \(\mathrm{Ce}^{4+}\) are diamagnetic in nature.
(iii) \(\mathrm{Ce}^{4+}\) can act as an oxidising agent
(iv) \(\operatorname{Ln}\) (III) compounds are generally colourless
(v) Ionic radii of \(\mathrm{Ce}^{3+}\) is greater than \(\mathrm{Yb}^{3+}\)

  1. A (i), (ii) and (iii)
  2. B (iii) and (iv)
  3. C (iii), (iv) and (v)
  4. D (i) and (iv)
Verified Solution

Answer & Solution

Correct Answer

(D) (i) and (iv)

Step-by-step Solution

Detailed explanation

Statement (i) is incorrect because basicity of lanthanide hydroxides decreases as the ionic radius decreases from \(\mathrm{La}^{3+}\) to \(\mathrm{Lu}^{3+}\). Thus, \(\mathrm{La}(\mathrm{OH})_3\) is the most basic, not the least basic. Statement (ii) is correct.…
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