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COMEDK · Chemistry · 25. Haloalkanes and Haloarenes

Consider the following reaction
\((\mathrm{CH}_3)_2 \mathrm{CHCH}_2 \mathrm{Br}+(\mathrm{CH}_3)_3 \mathrm{CCH}_2 \mathrm{Br} \xrightarrow[\Delta]{\mathrm{Na} \text { /dry ether }} \mathrm{X}+\mathrm{Y}+\mathrm{Z}\)
Identify the product which is not formed?

  1. A 2, 2, 5, 5-tetramethylhexane
  2. B 2, 2, 4, 4-tetramethylhexane
  3. C 2, 2, 5-trimethylhexane
  4. D 2, 5-dimethylhexane
Verified Solution

Answer & Solution

Correct Answer

(B) 2, 2, 4, 4-tetramethylhexane

Step-by-step Solution

Detailed explanation

The reaction is a Wurtz coupling reaction involving two different alkyl halides: R1-Br and R2-Br, where R1 is (CH3)2CHCH2- (isobutyl group) and R2 is (CH3)3CCH2- (neopentyl group). In a Wurtz reaction with a mixture of two different alkyl halides, the possible products are the…