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COMEDK · Chemistry · 18. Electrochemistry

Consider a Galvanic cell in which the following reactions occurs: \(\text{Fe}^{2+}(aq) + \text{Ag}^+(aq) \rightarrow \text{Fe}^{3+}(aq) + \text{Ag}(s)\). What is the standard potential of the cell? Given: \(E^0_{(\text{Ag}^+/\text{Ag})} = aV\), \(E^0_{(\text{Fe}^{2+}/\text{Fe})} = bV\) & \(E^0_{(\text{Fe}^{3+}/\text{Fe})} = cV\)

  1. A \((a + b + 2c)\,V\)
  2. B \((a + 2b - 3c)\,V\)
  3. C \((a - 2c + b)\,V\)
  4. D \((a + c - 2b)\,V\)
Verified Solution

Answer & Solution

Correct Answer

(B) \((a + 2b - 3c)\,V\)

Step-by-step Solution

Detailed explanation

The given cell reaction is \(\text{Fe}^{2+}(aq) + \text{Ag}^+(aq) \rightarrow \text{Fe}^{3+}(aq) + \text{Ag}(s)\). The standard cell potential is given by:…