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COMEDK · Chemistry · 23. d and f Block Elements

Choose the statements which are incorrect in the case of Lanthanoids.
A. \(\mathrm{Ce}^{4+}\) is diamagnetic while \(\mathrm{Sm}^{3+}\) is paramagnetic.
B. The atomic size of the transition metals having atomic number greater than 71 are very close to that of the elements above them.
C. Lanthanoids react with hot water forming water soluble \(\mathrm{Ln}(\mathrm{OH})_3\) with the liberation of \(\mathrm{O}_2\).
D. The general electronic configuration of Lanthanoids is \((n-2) f^{1-14} 5 d^0 6 s^2\), where \(n=6\).

  1. A B & D
  2. B C & D
  3. C A & B
  4. D A & D
Verified Solution

Answer & Solution

Correct Answer

(B) C & D

Step-by-step Solution

Detailed explanation

A. Correct: \(Ce^{4+}\) has \([Xe]4f^0\) configuration — all electrons paired, hence diamagnetic. \(Sm^{3+}\) has \([Xe]4f^5\) — unpaired \(f\)-electrons, hence paramagnetic. B. Correct: Due to lanthanoid contraction (poor shielding by \(4f\) electrons), the 5d transition…