COMEDK · Chemistry · 23. d and f Block Elements
Choose the statements which are incorrect in the case of Lanthanoids.
A. \(\mathrm{Ce}^{4+}\) is diamagnetic while \(\mathrm{Sm}^{3+}\) is paramagnetic.
B. The atomic size of the transition metals having atomic number greater than 71 are very close to that of the elements above them.
C. Lanthanoids react with hot water forming water soluble \(\mathrm{Ln}(\mathrm{OH})_3\) with the liberation of \(\mathrm{O}_2\).
D. The general electronic configuration of Lanthanoids is \((n-2) f^{1-14} 5 d^0 6 s^2\), where \(n=6\).
- A B & D
- B C & D
- C A & B
- D A & D
Answer & Solution
Correct Answer
(B) C & D
Step-by-step Solution
Detailed explanation
A. Correct: \(Ce^{4+}\) has \([Xe]4f^0\) configuration — all electrons paired, hence diamagnetic. \(Sm^{3+}\) has \([Xe]4f^5\) — unpaired \(f\)-electrons, hence paramagnetic. B. Correct: Due to lanthanoid contraction (poor shielding by \(4f\) electrons), the 5d transition…
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- The wavelength absorbed by the complex \([Cu(H_2O)_4]^{2+}\) (assuming tetrahedral geometry) for the d-d transition is 600 nm. The crystal field splitting energy for the complex \([Cu(H_2O)_6]^{2+}\) is:
[Given: \(h = 6.626 \times 10^{-34}\text{ Js}\), \(c = 3 \times 10^8\text{ ms}^{-1}\), and \(1\text{ eV} = 1.6 \times 10^{-19}\text{ J}\)]COMEDK 2025 Medium - In the Molisch reagent, the substance used isCOMEDK 2019 Medium
- What would be the products obtained when a mixture of p-Methoxy benzaldehyde and Methanal are heated with \(50 \%\) concentrated Caustic soda solution?COMEDK 2023 Medium
- For a reaction, \(2 A+B \longrightarrow\) products,
If concentration of \(B\) is kept constant and concentration of \(A\) is doubled then rate of reaction isCOMEDK 2023 Easy - Consider the gaseous equilibrium
\(2\text{AB}_{2(g)} \rightleftharpoons 2\text{AB}_{(g)} + \text{B}_{2(g)}\)
The expression relating the degree of dissociation (\(\alpha\)) and equilibrium constant (\(K_p\)) and total pressure P is:COMEDK 2026 Medium - Choose the incorrect statement.COMEDK 2025 Medium
More PYQs from COMEDK
- \(\lim _{n \rightarrow \infty} \frac{\left(1^{2}+2^{2}+\ldots+n^{2}\right) \sqrt[n]{n}}{(n+1)(n+10)(n+100)}=\)COMEDK 2018 Easy
- One end of the string of length \(l\) is connected to a particle of mass \(m\) and the other end is connected to a small peg on a smooth horizontal table. If the particle moves in circle with speed \(v\), the net force on the particle (directed towards centre) will be ( \(T\) represents the tension in the string)COMEDK 2023 Easy
- When 2-butyne is treated with dilute \(\text{H}_2\text{SO}_4/\text{HgSO}_4\), the product formed is:COMEDK 2026 Medium
- If frequencies are \((v-1)\) and \((v+2)\), then find the value of beats.COMEDK 2021 Easy
- 85 . The radius of an atom is \(300 \mathrm{pm}\). If it crystallises in a face-centered cubic lattice, the length of the edge of the unit cell isCOMEDK 2014 Easy
- If \(A, B\) and \(C\) are three mutually exclusive and exhaustive events such that \(P(A)=2 P(B)=3 P(C)\). What is \(P(B)\) ?COMEDK 2022 Medium