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COMEDK · Chemistry · 24. Coordination Compounds

Choose the incorrect statement from the following.

  1. A A tetrahedral complex of the type \([\mathrm{Ma}_2 \mathrm{b}_2]\) does not show geometrical isomerism
  2. B In a coordination entity of the type \([\mathrm{Ma} 2(\mathrm{bb})_2]^{2+}\) only the cis-isomer is optically active
  3. C Coordination entities of the type \([\mathrm{Ma}_3 \mathrm{b}_3]\) do not exhibit geometrical isomerism
  4. D Square planar complex  of the type [Mabcd] has 3 possible geometrical isomers
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Correct Answer

(C) Coordination entities of the type \([\mathrm{Ma}_3 \mathrm{b}_3]\) do not exhibit geometrical isomerism

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Detailed explanation

In a tetrahedral complex of the type \([Ma_2b_2]\), all positions are equivalent relative to each other, meaning there is no distinction between cis and trans positions. Thus, it does not show geometrical isomerism. This statement is correct. For a coordination entity of the…
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