COMEDK · Chemistry · 23. d and f Block Elements
Choose the correct metal/ ion from the brackets which ..........
A. has chemical reactivity similar to that of the first few members of the Lanthanoids \((\mathrm{Zn}, \mathrm{Ca}, \mathrm{Fe}, \mathrm{Cu})\).
B. has stable \(4 \mathrm{f}^7\) electronic configuration, but acts as a strong reducing agent and converts to \(\mathrm{M}^{3+}\) state. \(\left(\mathrm{Eu}^{2+}, \mathrm{Ce}^{2+}, \mathrm{Pr}^{2+}, \mathrm{Dy}^{2+}\right)\)
C. is a colorless ion \(\left(\mathrm{Tm}^{3+}, \mathrm{Lu}^{3+}, \mathrm{Gd}^{3+}, \mathrm{Sm}^{3+}\right)\).
D. shows stable +2 oxidation state and is diamagnetic \((\mathrm{Ce}, \mathrm{Sm}, \mathrm{Ho}, \mathrm{Yb})\)
- A \(\mathrm{A}: \mathrm{Zn} \quad \mathrm{B}: \mathrm{Ce}^{2+}, \quad \mathrm{C}:\mathrm{Gd}^{3+} \quad \mathrm{D}: \mathrm{Sm}\)
- B \(\mathrm{A}: \mathrm{Ca} \quad \mathrm{B}: \mathrm{Eu}^{2+}
\quad \mathrm{C}: \mathrm{Lu}^{3+}
\quad \mathrm{D}: ~ \mathrm{Yb}\) - C \(\mathrm{A}: \mathrm{Fe} \quad \mathrm{B}: \mathrm{Pr}^{2+}
\quad \mathrm{C}: \mathrm{Tm}^{3+}
\quad \mathrm{D}: ~ \mathrm{Ce}\) - D \(\mathrm{A}: \mathrm{Cu} \quad \mathrm{B}: \mathrm{Dy}^{2+}
\quad \mathrm{C}: \mathrm{Sm}^{3+}
\quad \mathrm{D}: ~ \mathrm{Ho}\)
Answer & Solution
Correct Answer
(B) \(\mathrm{A}: \mathrm{Ca} \quad \mathrm{B}: \mathrm{Eu}^{2+}
\quad \mathrm{C}: \mathrm{Lu}^{3+}
\quad \mathrm{D}: ~ \mathrm{Yb}\)
Step-by-step Solution
Detailed explanation
A. The lanthanoids are highly reactive metals, similar to calcium. Among the choices, calcium (Ca) exhibits chemical reactivity comparable to the early lanthanoids. B. Europium (Eu) has the electronic configuration \([Xe] 4f^7 6s^2\). The ion \(\mathrm{Eu}^{2+}\) has a stable…
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