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COMEDK · Chemistry · 23. d and f Block Elements

Choose the correct metal/ ion from the brackets which ..........
A. has chemical reactivity similar to that of the first few members of the Lanthanoids \((\mathrm{Zn}, \mathrm{Ca}, \mathrm{Fe}, \mathrm{Cu})\).
B. has stable \(4 \mathrm{f}^7\) electronic configuration, but acts as a strong reducing agent and converts to \(\mathrm{M}^{3+}\) state. \(\left(\mathrm{Eu}^{2+}, \mathrm{Ce}^{2+}, \mathrm{Pr}^{2+}, \mathrm{Dy}^{2+}\right)\)
C. is a colorless ion \(\left(\mathrm{Tm}^{3+}, \mathrm{Lu}^{3+}, \mathrm{Gd}^{3+}, \mathrm{Sm}^{3+}\right)\).
D. shows stable +2 oxidation state and is diamagnetic \((\mathrm{Ce}, \mathrm{Sm}, \mathrm{Ho}, \mathrm{Yb})\)

  1. A \(\mathrm{A}: \mathrm{Zn} \quad \mathrm{B}: \mathrm{Ce}^{2+}, \quad \mathrm{C}:\mathrm{Gd}^{3+} \quad \mathrm{D}: \mathrm{Sm}\)
  2. B \(\mathrm{A}: \mathrm{Ca} \quad \mathrm{B}: \mathrm{Eu}^{2+}
    \quad \mathrm{C}: \mathrm{Lu}^{3+}
    \quad \mathrm{D}: ~ \mathrm{Yb}\)
  3. C \(\mathrm{A}: \mathrm{Fe} \quad \mathrm{B}: \mathrm{Pr}^{2+}
    \quad \mathrm{C}: \mathrm{Tm}^{3+}
    \quad \mathrm{D}: ~ \mathrm{Ce}\)
  4. D \(\mathrm{A}: \mathrm{Cu} \quad \mathrm{B}: \mathrm{Dy}^{2+}
    \quad \mathrm{C}: \mathrm{Sm}^{3+}
    \quad \mathrm{D}: ~ \mathrm{Ho}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(\mathrm{A}: \mathrm{Ca} \quad \mathrm{B}: \mathrm{Eu}^{2+}
\quad \mathrm{C}: \mathrm{Lu}^{3+}
\quad \mathrm{D}: ~ \mathrm{Yb}\)

Step-by-step Solution

Detailed explanation

A. The lanthanoids are highly reactive metals, similar to calcium. Among the choices, calcium (Ca) exhibits chemical reactivity comparable to the early lanthanoids. B. Europium (Eu) has the electronic configuration \([Xe] 4f^7 6s^2\). The ion \(\mathrm{Eu}^{2+}\) has a stable…