COMEDK · Chemistry · 24. Coordination Compounds
Based on Valence Bond Theory, match the complexes listed in Column I with the number of unpaired electrons on the central metal ion, given in Column II
| No. | Complex ions | No. | Number of unpaired electrons |
|---|---|---|---|
| A | \([FeF_6]^{3-}\) | P | 0 |
| B | \([Fe(CN)_6]^{4-}\) | Q | 1 |
| C | \([Fe(H_2O)_6]^{2+}\) | R | 5 |
| D | \([Fe(CN)_6]^{3-}\) | S | 4 |
- A \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q}\)
- B \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}\)
- C \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{Q} \quad \mathrm{C}=\mathrm{R} \quad \mathrm{D}=\mathrm{P}\)
- D \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{Q} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{R}\)
Answer & Solution
Correct Answer
(A) \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q}\)
Step-by-step Solution
Detailed explanation
For \(\left[\mathrm{Fe} \mathrm{F}_6\right]^{3-}\), the oxidation state of Fe is \(+3\). The electronic configuration of \(\mathrm{Fe}^{3+}\) is \([\mathrm{Ar}] 3d^5\). Since \(\mathrm{F}^{-}\) is a weak field ligand, it does not cause pairing. Thus, there are \(5\) unpaired…
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