COMEDK · Chemistry · 24. Coordination Compounds
Based on Crystal Field theory, match the Complex ions listed in Column I with the electronic configuration in the d orbitals of the central metal ion listed in Column II.
| No. | Complex | No. | d orbital configuration of central metal ion |
|---|---|---|---|
| A | \([Mn(CN)_6]^{4-}\) | P | \(e_g^2 t_{2g}^3\) |
| B | \([Co(H_2O)_6]^{2+}\) | Q | \(t_{2g}^4 e_g^2\) |
| C | \([Fe(H_2O)_6]^{2+}\) | R | \(t_{2g}^5\) |
| D | \([MnCl_4]^{2-}\) | S | \(t_{2g}^5 e_g^2\) |
- A \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}\)
- B \(\mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q}\)
- C \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q}\)
- D \(\mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{R}\)
Answer & Solution
Correct Answer
(A) \(\mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P}\)
Step-by-step Solution
Detailed explanation
For \(\left[Mn(CN)_6\right]^{4-}\), the oxidation state of \(Mn\) is \(+2\). The electronic configuration of \(Mn^{2+}\) is \(3d^5\). Since \(CN^{-}\) is a strong field ligand, pairing occurs. The configuration is \(t_{2g}^5 e_g^0\), which is represented by (R). For…
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- The number of antibonding electron pairs in \(\mathrm{O}_{2}^{2-}\) molecular ion on the basis of molecular orbital theory is
[Atomic number of \(\mathrm{O}\) is 18 ]COMEDK 2020 Medium - What is the IUPAC name of following compound?
COMEDK 2021 Easy - Which one of the following is a true statement with reference to reaction between 2- Bromo-2-methylpropane and aqueous KOH ?COMEDK 2025 Medium
- The pH at which an acid indicator with \(K_\alpha=1 \times 10^{-5}\) changes colour when the indicator concentration is \(1 \times 10^{-3} \mathrm{M}\) isCOMEDK 2024 Easy
- Which of the following series of transitions in the spectrum of hydrogen atom fall in visible region?COMEDK 2021 Medium
- When chlorine is passed through boiling toluene, we getCOMEDK 2019 Medium
More PYQs from COMEDK
- Two cells with the same emf \(E\) and different internal resistances \(r_1\) and \(r_2\) are connected in series to an external resistance \(R\). If the potential difference across the first cell is zero then value of \(R\).COMEDK 2023 Medium
- The compounds \(A\) and \(B\) are mixed in equimolar proportion to form the products, \(A+B \rightleftharpoons C+D\). At equilibrium, one-third of \(A\) and \(B\) are consume(d) The equilibrium constant for the reaction isCOMEDK 2016 Hard
- A triangular park is enclosed on two sides by a fence and on the third side by a straight river bank. The two sides having fence are of same length \(x\). The maximum area enclosed by the park isCOMEDK 2023 Medium
- Two statements, one Assertion and the other Reason are given. Choose the right option.
Assertion: Insulin is called a protein whereas Glycyl alanine is not called a protein
Reason: A polypeptide with amino acid residue less than 100 can also be called as a protein if it has a well-defined conformation of a protein.COMEDK 2025 Medium - The direction cosines of the vector \(2 \hat{\mathbf{i}}+\hat{\mathbf{j}}-2 \hat{\mathbf{k}}\) is equal toCOMEDK 2012 Easy
- If in the expansion of \((1+p x)^{n}, n \in N\), the coefficient of \(x\) and \(x^{2}\) are 8 and 24 , thenCOMEDK 2015 Medium