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COMEDK · Chemistry · 3. Classification of Elements and Periodicity in Properties

Atomic numbers of vanadium, chromium, nickel and iron are \(23,24,28\) and 26 respectively. Which one of these is expected to have the highest second ionisation enthalpy?

  1. A \(\mathrm{Cr}\)
  2. B \(\mathrm{V}\)
  3. C \(\mathrm{Fe}\)
  4. D \(\mathrm{Ni}\)
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Answer & Solution

Correct Answer

(A) \(\mathrm{Cr}\)

Step-by-step Solution

Detailed explanation

Second ionisation enthalpy of \(\mathrm{Cr}\) is highest because after the removal of 1st electron, Cr acquires a stable half-filled \(d^{5}\) configuration thus, removal of 2 nd electron is very difficult.