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COMEDK · Chemistry · 19. Chemical Kinetics

At \(300 \mathrm{~K}\), the half-life period of a gaseous reaction at an initial pressure of \(40 \mathrm{~kPa}\) is 350 s. When pressure is \(20 \mathrm{~kPa}\), the half-life period is 175 s. What is the order of the reaction?

  1. A Three
  2. B One
  3. C Two
  4. D Zero
Verified Solution

Answer & Solution

Correct Answer

(D) Zero

Step-by-step Solution

Detailed explanation

For a gaseous reaction of order \(n\), the half-life \(t_{1/2}\) is related to the initial pressure \(P_0\) by the relation \(t_{1/2} \propto \dfrac{1}{P_0^{n-1}}\). Given data: Case 1: \(P_{0,1} = 40 \text{ kPa}\), \(t_{1/2,1} = 350 \text{ s}\) Case 2:…