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COMEDK · Chemistry · 14. Hydrocarbons

Arrange the following compounds in the decreasing order of reactivity towards electrophilic substitution reaction.
(I) Chlorobenzene
(II) Nitrobenzene
(III) Benzene
(IV) Isopropylbenzene

  1. A \(\mathrm{I}>\mathrm{II}>\mathrm{IV}>\mathrm{III}\)
  2. B \(\text { IV }>\text { III }>\text { I }>\text { II }\)
  3. C \(\mathrm{IV}>\mathrm{I}>\mathrm{II}>\mathrm{III}\)
  4. D \(\mathrm{III}>\mathrm{II}>\mathrm{IV}>\mathrm{I}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(\text { IV }>\text { III }>\text { I }>\text { II }\)

Step-by-step Solution

Detailed explanation

The reactivity of benzene derivatives towards electrophilic aromatic substitution depends on the nature of the substituent attached to the benzene ring. Electron-donating groups (EDG) increase the electron density of the ring, making it more reactive, while electron-withdrawing…