COMEDK · Chemistry · 17. Solutions
An aqueous solution of an electrolyte \(\text{A}_3\text{B}\) is prepared by dissolving 0.5625 moles in 750 ml of water and is found to be 80% ionised. If \(\text{K}_\text{b}\) for water is \(0.52\text{ K kg mol}^{-1}\), calculate the boiling point of the solution at 1.0 atm pressure.
(Assume the boiling point of pure water is 373 K).
- A 373.18 K
- B 371.68 K
- C 374.33 K
- D 377.2 K
Answer & Solution
Correct Answer
(C) 374.33 K
Step-by-step Solution
Detailed explanation
Molality: \(m = \dfrac{0.5625}{0.75} = 0.75\) m \(A_3B\) dissociates into 4 ions, \(n = 4\), \(\alpha = 0.8\) Van't Hoff factor: \(i = 1 + (n-1)\alpha = 1 + 3 \times 0.8 = 3.4\) \(\Delta T_b = i \cdot K_b \cdot m = 3.4 \times 0.52 \times 0.75 = 1.326\) K…
See the Complete Solution
Get step-by-step explanations for this and 2.5 Lakh+ more JEE, NEET & CET questions.
- Unlock all solutions
- Practice the full chapter
- Track accuracy across PYQs
4.8 rated on Google Play · 14,000+ reviews
More questions from Chemistry
- ............ is unstable at cooking temperature, whereas the control of sweetness of food is difficult while using .........COMEDK 2022 Easy
- Pure water is neutral becauseCOMEDK 2019 Easy
- Which of the following is the correct sequence of relative acidic strength?COMEDK 2015 Medium
- For an adiabatic change in a system, the condition which is applicable isCOMEDK 2023 Easy
- Which one of the following coordination compounds will exhibit both geometrical and optical isomerism?COMEDK 2025 Medium
- An organic compound [X] (Molecular formula \(\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_2\) ) reacts with dil. \(\mathrm{H}_2 \mathrm{SO}_4\) to form an alcohol [B] and a carboxylic acid [C]. Reaction of compound \([\mathrm{B}]\) with Jones reagent yielded compound \([\mathrm{C}]\). When compound \([\mathrm{C}]\) was heated with \(\mathrm{P}_2 \mathrm{O}_5\) an Anhydride was formed. Compound \([\mathrm{X}]\) is ________.COMEDK 2025 Medium
More PYQs from COMEDK
- A wire of length 1m has a resistance of \(20\ \Omega\) at \(0^\circ\)C. It is uniformly stretched so that its length increases by 21%. Assuming the volume of the wire remains constant, the percentage change in resistance is \(n\%\). Alternatively, if the wire is heated [without stretching] through a temperature of \(27^\circ\) C and if the temperature coefficient of resistance of the material of wire is \(0.004K^{-1}\), the percentage change in resistance is \(m\%\). The values of \(m\) and \(n\) are:COMEDK 2026 Medium
- A square wire of each side l carries a current \(I\). The magnetic field at the mid-point of the square
COMEDK 2023 Medium - A car, starting from rest, accelerates at a rate of \(\beta\) through a distance S, then continues at constant speed for time t and then decelerates at a rate of \(\dfrac{\beta}{2}\) to come to rest. If the total distance travelled is \(10\ S\), then ratio \(\dfrac{S}{t^2}\) isCOMEDK 2026 Medium
- Choose the correct metal/ ion from the brackets which ..........
A. has chemical reactivity similar to that of the first few members of the Lanthanoids \((\mathrm{Zn}, \mathrm{Ca}, \mathrm{Fe}, \mathrm{Cu})\).
B. has stable \(4 \mathrm{f}^7\) electronic configuration, but acts as a strong reducing agent and converts to \(\mathrm{M}^{3+}\) state. \(\left(\mathrm{Eu}^{2+}, \mathrm{Ce}^{2+}, \mathrm{Pr}^{2+}, \mathrm{Dy}^{2+}\right)\)
C. is a colorless ion \(\left(\mathrm{Tm}^{3+}, \mathrm{Lu}^{3+}, \mathrm{Gd}^{3+}, \mathrm{Sm}^{3+}\right)\).
D. shows stable +2 oxidation state and is diamagnetic \((\mathrm{Ce}, \mathrm{Sm}, \mathrm{Ho}, \mathrm{Yb})\)COMEDK 2025 Hard - The change in the energy of system if \(500 \mathrm{cal}\) of heat energy are added to a system and system does \(350 \mathrm{cal}\) of work on the surroundings will beCOMEDK 2021 Medium
- The temperature of one mole of an ideal gas increases from \(298 \mathrm{~K}\) to \(308 \mathrm{~K}\), when it absorbs \(200 \mathrm{~J}\) of heat at constant volume. The change in the internal energy of the gas isCOMEDK 2012 Medium