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COMEDK · Chemistry · 26. Alcohols Phenols and Ethers

4 statements are given below. Identify the incorrect statement
A. Phenol has lower \(\mathrm{pK}_{\mathrm{a}}\) value than \(\mathrm{p}\)-cresol
B. 2-Chlorophenol is more acidic than phenol
C. Ortho and para nitrophenols can be separated by steam distillation since \(\mathrm{p}\)-Nitrophenol is more steam volatile than o-Nitrophenol
D. Phenol on reaction with \(\dfrac{\mathrm{Cr}_2 \mathrm{O}_7^{2-}}{\mathrm{H}^{+}}\) yields a conjugated diketone

  1. A C
  2. B A
  3. C D
  4. D B
Verified Solution

Answer & Solution

Correct Answer

(A) C

Step-by-step Solution

Detailed explanation

Statement A is correct because the electron-donating methyl group in p-cresol decreases the acidity of the phenolic hydroxyl group compared to phenol, leading to a higher pKa value for p-cresol and a lower pKa value for phenol. Statement B is correct because the…