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AP EAMCET · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Which of the following represents correct order of oxidising power of halogens with water?

  1. A \(\mathrm{I}_2>\mathrm{Br}_2>\mathrm{Cl}_2>\mathrm{F}_2\)
  2. B \(\mathrm{Cl}_2>\mathrm{F}_2>\mathrm{Br}_2>\mathrm{I}_2\)
  3. C \(\mathrm{F}_2>\mathrm{Cl}_2>\mathrm{I}_2>\mathrm{Br}_2\)
  4. D \(\mathrm{F}_2>\mathrm{Cl}_2>\mathrm{Br}_2>\mathrm{I}_2\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(\mathrm{F}_2>\mathrm{Cl}_2>\mathrm{Br}_2>\mathrm{I}_2\)

Step-by-step Solution

Detailed explanation

Whenever one of the halogens is involved in oxidising a species in solution, the halogen is reduced to a halide ion associated with water molecules. The following reactions illustrate this process \({ }^{\circ}\) \(\mathrm{F}_2(g)+2 e^{-} \longrightarrow 2 \mathrm{~F}^{-}(a q)\)…