AP EAMCET · Chemistry · Alcohols Phenols and Ethers
The products formed in the reaction of phenol with \(\mathrm{Br}_2\) dissolved in \(\mathrm{CS}_2\) at \(0^{\circ} \mathrm{C}\) are
- A \(o\)-bromo, \(m\)-bromo and \(p\)-bromophenols
- B o-bromo and \(p\)-bromophenols
- C 2,4,6-tribromo and 2,3,6-tribromophenols
- D 2,4-dibromo and 2,6-dibromophenols
Answer & Solution
Correct Answer
(B) o-bromo and \(p\)-bromophenols
Step-by-step Solution
Detailed explanation
Phenol when treated with \(\mathrm{Br}_2\) in the presence of non-polar solvent \(\mathrm{CS}_2\), it gives only o- and \(p\)-bromophenols instead the trisubstituted products. Reason for the above observation is supression of phenoxide ion in non-polar solvent. Thus, we get only…
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