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AP EAMCET · Chemistry · Haloalkanes and Haloarenes

The product of which of the following reactions undergo hydrolysis by \(\mathrm{S}_{\mathrm{N}} 1\) mechanism?

  1. A C, D only
  2. B A, B, C only
  3. C \(\mathrm{B}, \mathrm{C}\) only
  4. D A, D only
Verified Solution

Answer & Solution

Correct Answer

(C) \(\mathrm{B}, \mathrm{C}\) only

Step-by-step Solution

Detailed explanation

So only (B) and (C) formed stable benzylic carbocation so it will undergo hydrolysis by \(\mathrm{S}_{\mathrm{N}} 1\) mechanism. \(\mathrm{S}_{\mathrm{N}} 1\) reactivity order : benzylic \(\gt3^{\circ}\gt2^{\circ}\gt1^{\circ}\) \(\mathrm{S}_{\mathrm{N}} 2\) reactivity order :…