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AP EAMCET · Chemistry · Classification of Elements and Periodicity in Properties

The formation of oxide ion \(\mathrm{O}^{2-}\) from oxygen atom requires an exothermic reaction, followed by an endothermic step as shown below. The process of formation of \(\mathrm{O}^{2-}\) in gas phase is unfavorable \(\left(\Delta H^{\ominus}=+\right.\) ve \()\), even though it has stable configuration of the nearest noble gas neon. This is because
\(\begin{aligned} & \mathrm{O}(g)+e^{-} \longrightarrow \mathrm{O}^{-}(g) ; \Delta H^{\ominus}=-141 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ & \mathrm{O}^{-}(g)+e^{-} \longrightarrow \mathrm{O}^{2-}(g) ; \Delta H^{\ominus}=+760 \mathrm{~kJ} \mathrm{~mol}^{-1}\end{aligned}\)

  1. A \(\mathrm{O}^{2-}\) has larger size than that of neon
  2. B oxygen is more electronegative than neon
  3. C \(\mathrm{O}^{2-}\) has larger size than oxygen atom
  4. D electron repulsion in oxide ion is more which over comes the stability achieved by noble gas configuration.
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(D) electron repulsion in oxide ion is more which over comes the stability achieved by noble gas configuration.

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The process of formation of \(\mathrm{O}^{2-}\) in the gas phase is unfavorable even through \(\mathrm{O}^{2-}\) is isoelectronic with neon. It is due to that electronic repulsion outweighs the stability gained by achieving noble gas configuration. The formation of oxide ion,…
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