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AP EAMCET · Chemistry · Coordination Compounds

In which of the following, complex ions are not in correct order with respect to their magnitude of crystal field splitting ?

  1. A \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}>\left[\mathrm{FeF}_6\right]^{3-}\)
  2. B \(\left[\mathrm{Fe}(\mathrm{en})_3\right]^{3+}>\left[\mathrm{Fe}(\mathrm{NCS})_6\right]^{3-}\)
  3. C \(\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}>\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}\)
  4. D \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}>\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right]^{2+}\)
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(D) \(\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}>\left[\mathrm{Fe}\left(\mathrm{NH}_3\right)_6\right]^{2+}\)

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