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AP EAMCET · Chemistry · General Organic Chemistry

In Dumas method one gram of carbon compound gives \(50 \mathrm{~mL}\) of \(\mathrm{N}_2\) at \(300 \mathrm{~K}\) and \(740 \mathrm{~mm} \mathrm{Hg}\) pressure. If the aqueous tension at \(300 \mathrm{~K}\) is \(15 \mathrm{~mm} \mathrm{Hg}\), what is the percentage of nitrogen in it?

  1. A 42
  2. B 10.84
  3. C 21.68
  4. D 2.71
Verified Solution

Answer & Solution

Correct Answer

(A) 42

Step-by-step Solution

Detailed explanation

Given, \(p=740 \mathrm{~mm}\) of \(\mathrm{Hg}\) dry gas pressure \(p_1=740-15=725 \mathrm{~mm} \mathrm{Hg}\) \(V_1=50 \mathrm{~mL}\) \(T_1=300 \mathrm{~K}, p_2=760 \mathrm{~mm} \mathrm{Hg}, T_2=273 \mathrm{~K}\) From the combine gas equation,…