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AP EAMCET · Chemistry · Thermodynamics (C)

Identify the correct statements from the following
I. \(\Delta_{\mathrm{r}} \mathrm{G}\) is zero for \(\mathrm{A} \rightleftharpoons \mathrm{B}\) reaction
II. The entropy of pure crystalline solids approaches zero as the temperature approaches absolute zero
III. \(\Delta U\) of a reaction can be determined using bomb calorimeter

  1. A I, II only
  2. B I, III only
  3. C II, III only
  4. D I, II, III
Verified Solution

Answer & Solution

Correct Answer

(D) I, II, III

Step-by-step Solution

Detailed explanation

(I) For equilibrium reaction Gibb's free energy i.e \(\Delta \mathrm{G}_{\mathrm{r}}=0\) (II) According to third law of thermodynamics, the entropy of pure crystalline solid approaches zero as the temperature approaches absolute zero. This is because there is perfect order in a…